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Ethyl phenyl acetate Basic information

Product Name:	Ethyl phenyl acetate
CAS:	101-97-3
MF:	C10H12O2
MW:	164.2
EINECS:	202-993-8
Mol File:	101-97-3.mol

Ethyl phenyl acetate Chemical Properties

Melting point	-29 °C
Boiling point	229 °C(lit.)
density	1.03 g/mL at 25 °C(lit.)
FEMA	2452 \| ETHYL PHENYLACETATE
refractive index	n20/D 1.497(lit.)
Fp	172 °F
storage temp.	Store below +30°C.
form	neat
Water Solubility	insoluble
Merck	14,3840
JECFA Number	1009
BRN	509140
InChIKey	DULCUDSUACXJJC-UHFFFAOYSA-N
CAS DataBase Reference	101-97-3(CAS DataBase Reference)
NIST Chemistry Reference	Benzeneacetic acid, ethyl ester(101-97-3)
EPA Substance Registry System	Benzeneacetic acid, ethyl ester (101-97-3)

Ethyl phenyl acetate Safety Information

Safety Statements	23-24/25
WGK Germany	2
RTECS	AJ2824000
TSCA	Yes
HS Code	29163500

Ethyl phenyl acetate Usage And Synthesis

Chemical Properties	Ethyl Phenylacetate is a volatile aroma component of fruit and honey. It is a colorless liquid with a strong, sweet odor reminiscent of honey. Small amounts are used in flower perfumes and in fruit flavors.
Chemical Properties	Ethyl phenylacetate has a pleasant, strong, sweet odor suggestive of honey and a bittersweet flavor.
Chemical Properties	clear colourless to pale yellowish liquid
Occurrence	Reported found in grapefruit juice, apple juice, figs, guava, pineapple, papaya, cognac, cider, grape wines and port wine.
Uses	In perfumery.
Preparation	By heating at the boil phenylacetonitrile and sulfuric acid in alcohol solution; by esterification of the acid catalyzed by HCl or H2SO4
Aroma threshold values	Detection: 650 ppb
Taste threshold values	Taste characteristics at 10 ppm: sweet, fruity, honey, cocoa, apple and woody
Safety Profile	Moderately toxic by ingestion. Combustible liquid. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
Purification Methods	Shake the ester with saturated aqueous Na2CO3 (three times), aqueous 50% CaCl2 (twice) and saturated aqueous NaCl (twice). Dry with CaCl2 and distil it under reduced pressure. [Beilstein 9 H 434, 9 IV 1618.]

Ethyl phenyl acetate Preparation Products And Raw materials

Preparation Products	Phenethyl alcohol-->Acetamide-->Phenthoate-->2-PHENYLMALONAMIDE-->Phenobarbital-->Diethyl 2-ethyl-2-phenylmalonate-->BUCILLAMINE-->1-Phenyl-1-cyclopropanecarboxylic acid-->ETHYL ALPHA-CHLOROPHENYLACETATE-->Diethyl phenylmalonate-->ETHYL A-ETHOXYOXALYLPHENYL ACETATE-->Ethyl alpha-Formyl Benzeneacetic Acid Ester-->Leucoson
Raw materials	Benzeneacetonitrile-->Phenylacetic acid-->2-Phenylacetamide

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